A Search for ortho -benzyne ( o -C 6 H 4 ) in CRL 618

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A SEARCH FOR ortho - BENZYNE ( o - C 6 H 4 ) IN CRL 618 Susanna

Polycyclic aromatic hydrocarbons (PAHs) have been proposed as potential carriers of the unidentified infrared bands (UIRs) and the diffuse interstellar bands (DIBs). PAHs are not likely to form by gas-phase or solid-state interstellar chemistry, but rather might be produced in the outflows of carbon-rich evolved stars. PAHs could form from acetylene addition to the phenyl radical (C6H5), which ...

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A SEARCH FOR ortho - BENZYNE ( o - C 6 H 4 ) IN CRL 618

Polycyclic aromatic hydrocarbons (PAHs) have been proposed as potential carriers of the unidentified infrared bands (UIRs) and the diffuse interstellar bands (DIBs). PAHs are not likely to form by gas-phase or solid-state interstellar chemistry, but rather might be produced in the outflows of carbon-rich evolved stars. PAHs could form from acetylene addition to the phenyl radical (C6H5), which ...

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Unimolecular thermal fragmentation of ortho-benzyne.

The ortho-benzyne diradical, o-C(6)H(4) has been produced with a supersonic nozzle and its subsequent thermal decomposition has been studied. As the temperature of the nozzle is increased, the benzyne molecule fragments: o-C(6)H(4)+Delta--> products. The thermal dissociation products were identified by three experimental methods: (i) time-of-flight photoionization mass spectrometry, (ii) matrix...

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7 v 1 3 J an 2 00 0 H 2 emission from CRL 618

We present a complete study of the H 2 infrared emission, including the pure rotational lines, of the proto Planetary Nebulae CRL 618 with the ISO SWS. A large number of lines are detected. The analysis of our observations shows: (i) an OTP ratio very different from the classical value of 3, probably around 1.76-1.87; (ii) a stratification of the emitting region, and more precisely different re...

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Dynamics of reactions O((1)D)+C(6)H(6) and C(6)D(6).

The reaction between O((1)D) and C(6)H(6) (or C(6)D(6)) was investigated with crossed-molecular-beam reactive scattering and time-resolved Fourier-transform infrared spectroscopy. From the crossed-molecular-beam experiments, four product channels were identified. The major channel is the formation of three fragments CO+C(5)H(5)+H; the channels for formation of C(5)H(6)+CO and C(6)H(5)O+H from O...

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ژورنال

عنوان ژورنال: The Astrophysical Journal

سال: 2007

ISSN: 0004-637X,1538-4357

DOI: 10.1086/525042